解答:解:由n≥2时,an=3Sn可得Sn-sn-1=3Sn,从而知Sn=-12sn-1,∴{Sn}为首项是1,公比为-12的等比数列,∴limn→∞Sn+1Sn+1-3=limn→∞(-12)n-1+ 1(-12)n-3=-13,故选C.